About site: Chemistry/Chemistry Safety - S-Phrases

About site: http://www.chemie.fu-berlin.de/chemistry/safety/s-saetze_en.html

Title: Chemistry/Chemistry Safety - S-Phrases An index of the "S" Phrases. Used in European labs.

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S-Phrases

R-Phrases

LIST OF S-PHRASES

CONTENT:

S-Phrases Combinations of S-Phrases

HINTS:

Links of S-phrases point to the Council Directive 67/548/EEC (licence required for access.) You will find there notes (in German) on how to use the S-phrase. In this list you will also find some modifications of S-phrases made by manufacturers. These modifications are preceded by the company name.

S-PHRASES:

S1: Keep locked up. S2: Keep out of the reach of children. S3: Keep in a cool place. S4: Keep away from living quarters. S5: Keep contents under ... (appropriate liquid to be specified by the manufacturer). Merck S5.1: Keep contents under water. Merck S5.2: Keep contents under petroleum. Merck S5.3: Keep contents under paraffin oil. Riedel-de Haen S5A: Keep contents under paraffin oil. Riedel-de Haen S5B: Keep contents under petroleum. Riedel-de Haen S5C: Keep contents under protecting liquid. S6: Keep contents under ... (appropriate gas to be specified by the manufacturer). Merck S6.1: Keep contents under nitrogen. Merck S6.2: Keep contents under argon. Merck S6.3: Keep contnts under carbon dioxide. Riedel-de Haen S6A: Keep contents under protecting gas. Riedel-de Haen S6B: Keep contents under nitrogen. Riedel-de Haen S6C: Keep contents under argon. S7: Keep container tightly closed. S8: Keep container dry. S9: Keep container in a well-ventilated place. S10 (obsolete): Keep content wet. (This S-phrase is no longer designated by the version of the GefStoffV published on 26.10.93.) S11(obsolete): Avoid contact with air. (This S-phrase is no longer designated by the version of the GefStoffV published on 26.10.93.) S12: Do not keep the container sealed. S13: Keep away from food, drink and animal feedingstuffs. S14: Keep away from ... (incompatible materials to be indicated by the manufacturer) Merck S14.1: Keep away from reducing agents, heavy metal compounds, acids and alkalies. Merck S14.2: Keep away from oxidizing and acidic agents and heavy metal compounds. Merck S14.3: Keep away from iron. Merck S14.4: Keep away from water and lyes. Merck S14.5: Keep away from acids. Merck S14.6: Keep away from lyes. Merck S14.7: Keep away from metals. Merck S14.8: Keep away from oxidizing and acidic agents. Merck S14.9: Keep away from combustible organic compounds. Merck S14.10: Keep away from acids, reducing agents and combustible materials. Merck S14.11: Keep away from combustible material. (This is unnecessary because it equals S17!) S15: Keep away from heat. S16: Keep away from sources of ignition - No smoking. S17: Keep away from combustible material. S18: Handle and open container with care. S20: When using do not eat or drink. S21: When using do not smoke. S22: Do not breathe dust. S23: Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer). Merck S23.1: Do not breath gas. Merck S23.2: Do not breath vapour. Merck S23.3: Do not breath spray. Merck S23.4: Do not breath fumes. Merck S23.5: Do not breathe vapor/spray. Riedel-de Haen S23A: Do not breath gas. Riedel-de Haen S23B: Do not breath fumes. Riedel-de Haen S23C: Do not breath spray. S24: Avoid contact with skin. S25: Avoid contact with eyes. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S27: Take off immediately all contaminated clothing. S28: After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer). Merck S28.1: After contact with skin, wash immediately with plenty of water. Merck S28.2: After contact with skin, wash immediately with plenty of water and soap. Merck S28.3: After contact with skin, wash immediately with plenty of water and soap, if possible also with polyethylene glycol 400. Merck S28.4: After contact with skin, wash immediately with plenty of polyethylene glycol 300 and ethanol (2:1) and afterwards with plenty of water and soap. Merck S28.5: After contact with skin, wash immediately with plenty of polyethylene glycol 400. Merck S28.6: After contact with skin, wash immediately with plenty of polyethylene glycol 400 and afterwards clean with plenty of water. Merck S28.7: After contact with skin, wash immediately with plenty of water and acidic soap. Riedel-de Haen S28A: After contact with skin, wash immediately with plenty of a 2% copper(II)-sulfate solution . Riedel-de Haen S28B: After contact with skin, wash immediately with plenty of polyethylene glycol. Riedel-de Haen S28C: After contact with skin, wash immediately with plenty of polyethylene glycol / ethanol (1:1). Riedel-de Haen S28D: After contact with skin, wash immediately with plenty of water and soap. S29: Do not empty into drains. S30: Never add water to this product. S31 (obsolete): Keep away from explosive materials. (This S-phrase is no longer designated by the version of the GefStoffV published on 26.10.93.) S33: Take precautionary measures against static discharges. S34 (obsolete): Avoid strokes and frictions. (This S-phrase is no longer designated by the version of the GefStoffV published on 26.10.93.) S35: This material and its container must be disposed of in a safe way. Merck S35.1: This material and its container must be disposed of by treating with a 2% sodium hydroxide solution. S36: Wear suitable protective clothing. S37: Wear suitable gloves. S38: In case of insufficient ventilation, wear suitable respiratory equipment. S39: Wear eye/face protection. S40: To clean the floor and all objects contaminated by this material, use ... (to be specified by the manufacturer). Merck S40.1: To clean the floor and contaminated objects, use water. Riedel-de Haen S40A: To clean the floor and contaminated objects, use iodized active carbon. S41: In case of fire and/or explosion do not breathe fumes. S42: During fumigation/spraying wear suitable respiratory equipment (appropriate wording to be specified by the manufacturer) S43: In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases risk, add - 'Never use water') Merck S43.1: In case of fire use water. Merck S43.2: In case of fire use water or powder. Merck S43.3: In case of fire use fire powder. Never use water. Merck S43.4: In case of fire use carbon dioxide. Never use water. Merck S43.6: In case of fire use sand. Never use water. Merck S43.7: In case of fire use metal fire powder. Never use water. Merck S43.8: In case of fire use sand, carbon dioxide or fire powder. Never use water. Riedel-de Haen S43A: In case of fire use sand. Never use water. S44 (obsolete): If you feel unwell, seek medical advice immediately. (Show the label where possible.) (This S-phrase is no longer designated by the version of the GefStoffV published on 26.10.93.) S45: In case of accident or if you feel unwell, seek medical advice immediately. (Show the label where possible.) S46: If swallowed, seek medical advice immediately and show this container or label. S47: Keep at temperature not exceeding ... °C. (To be specified by the manufacturer.) FU-Safety data base S4730: Keep at temperature not exceeding 30 °C. FU-Safety data base S4740: Keep at temperature not exceeding 40 °C. S48: Keep wet with ... (appropriate material to be specified by the manufacturer) Merck S48.1: Keep wet with water. Riedel-de Haen S48A: Keep wet with water. S49: Keep only in the original container S50: Do not mix with ... (to be specified by the manufacturer) Merck S50.1: Do not mix with acids. Merck S50.2: Do not mix with lyes. Merck S50.3: Do not mix with strong acids or lyes, nonferrous heavy metals and their salts. S51: Use only in well-ventilated areas. S52: Not recommended for interior use on large surface areas. S53: Avoid exposure - obtain special instructions before use. S54 (obsolete): Before draining of to sewage disposal plant ask for permission of the competent authority. (This S-phrase is no longer designated by the version of the GefStoffV published on 26.10.93.) S55 (obsolete): Before draining of into the sewage system or into waters treat according to state of art. (This S-phrase is no longer designated by the version of the GefStoffV published on 26.10.93.) S56: Dispose of this material and its container at hazardous or special waste collection point. S57: Use appropriate container to avoid environmental contamination. S58 (obsolete): Dispose as hazardous waste. (This S-phrase is no longer designated by the version of the GefStoffV published on 26.10.93.) S59: Refer to manufacturer/supplier for information on recovery/recycling S60: This material and its container must be disposed of as hazardous waste. S61: Avoid release to the environment. Refer to special instructions / Safety data sheets. S62: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. S63: In case of accident by inhalation: remove casualty to fresh air and keep at rest. S64: If swallowed, rinse mouth with water (only if the person is conscious).

COMBINATIONS OF S-PHRASES:

S1/2: Keep locked up and out of the reach of children. S3/7: Keep container tightly closed in a cool place. S3/7/9 (obsolete): Keep container tightly closed in a cool, well-ventilated place. S3/9 (obsolete): Keep container in a cool, well-ventilated place. S3/9/14: Keep in a cool, well-ventilated place away from ... (incompatible materials to be indicated by the manufacturer) S3/9/14/49: Keep only in the original container in a cool, well-ventilated place away from ... (incompatible materials to be indicated by the manufacturer) S3/9/49: Keep only in the original container in a cool well-ventilated place. S3/14: Keep in a cool place away from ... (incompatible materials to be indicated by the manufacturer) S7/8: Keep container tightly closed and dry. S7/9: Keep container tightly closed and in a well-ventilated place. S7/47: Keep container tightly closed and at a temperature not exceeding ... °C (to be specified by the manufacturer). S20/21: When using do not eat, drink or smoke. S24/25: Avoid contact with skin and eyes. S27/28: Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of ......(to be specified by the manufacturer) S29/35: Do not empty into drains. This material and its container must be disposed of in a safe way. S29/56: Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. S36/37: Wear suitable protective clothing and gloves. S36/37/39: Wear suitable protective clothing, gloves and eye/face protection. S36/39: Wear suitable protective clothing and eye/face protection. S37/39: Wear suitable gloves and eye/face protection. S47/49: Keep only in the original container at a temperature not exceeding ... °C (to be specified by the manufacturer) Burkhard Kirste, 1994-07-08, Thomas Lehmann, 1996-01-02; last modification: 2004-04-16

An	index	of	the
"S"	Phrases.	Used	in	European
labs.

http://www.chemie.fu-berlin.de/chemistry/safety/s-saetze_en.html

S-Phrases 2008 December

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An index of the "S" Phrases. Used in European labs.

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